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Attack on the nitro group leads to radical XXXIII, which can react with other propagating O radicals (Eqs. 3-151 and 3-152) or cleave to nitrosobenzene and Mn radical (Eq. 3-153). Both nitrosobenzene and Mn can react with and terminate other propagating radicals. O

Modern forms of consumer credit outmoded the pawnshops, which became of far less relative importance than in the past These modern rates of interest on consumer credit must recall a number of earlier chapters of this history The 20% legal limit of Babylonia, the 24% rate charged in Ptolemaic Egypt, and the 8 12% legal limits.

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3-152 3-153

FIGURE C-20

THE UNITED STATES IN THE TWENTIETH CENTURY: 1946 1990

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The reaction in Eq. 3-152 probably also involves disproportionation hydrogen atom transfer from the propagating radical to XXXII. Overall, one observes high y values up to 5 or 6 for 1,3,5-trinitrobenzene. Oxidants such as FeCl3 and CuCl2 are strong inhibitors, terminating radicals by the reactions [Billingham et al., 1980; Chetia and Dass, 1976; Matsuo et al., 1977]:

Reductants also terminate propagating radicals, but much less effectively. Other inhibitors include sulfur, carbon, aromatic azo compounds, and chlorophosphines [Nigenda et al., 1977; Uemura et al., 1977].

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An especially interesting case of inhibition is the internal or autoinhibition of allylic mono CH mers (CH2 CH 2 Y). Allylic monomers such as allyl acetate polymerize at abnormally low rates with the unexpected dependence of the rate on the rst power of the initiator concentration. Further, the degree of polymerization, which is independent of the polymerization rate, is very low only 14 for allyl acetate. These effects are the consequence of degradative chain transfer (case 4 in Table 3-3). The propagating radical in such a polymerization is very reactive, while the allylic C (the C bond alpha to the double bond) in the monomer is H H quite weak resulting in facile chain transfer to monomer

of Rome were within our modern range for consumer credit; so was the 15% charged by the charitable pawnshops of the Middle Ages. So-called truth in lending legislation, passed early in the 1970 s for the first time, required lenders to provide borrowers with the true annual percentage rate of interest implicit in consumer and other forms of credit. This has made it possible to gather and publish nationwide data on the average rates charged on important categories of consumer credit. Table 58 and Chart 49 present several such average annual rates from 1972 through 1989. The pattern of new automobile and personal loan rates conforms in general to the pattern of money and bond market rates over this period, but these rates behave more sluggishly than do the open market rates, being slower to rise when market rates are trending up and slower to fall when market rates fall. Credit card plan rates, in contrast, on average moved barely at all in relation to other rates during a period that witnessed the greatest fluctuations in money and bond market rates in U.S. history. Some of what was said earlier about the reasons for the relative stability of mortgage rates, at least before government intervention and securitization, applies also to consumer credit. The published rates contain large cost components that do not vary much, even as open market rates swing up and down. That is an important part of the explanation of why consumer credit rates are both higher and more stable over time than market rates.

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Electrical ground is indicated by the dashed triangle. A convention to help simplify schematic diagrams, this symbol eliminates the clutter of all the lines otherwise needed to indicate where wires would attach to the common, or ground, side of the circuit (many points in circuits often connect to ground). But what is ground While an earth ground is called for in some electronic applications (like grounding an antenna tower by actually running a wire from it to a spike driven into the earth), for us ground is simply the negative side of the circuit. Accordingly, all points on a circuit terminated in a ground symbol are to be connected to the negative (-) side of the power supply. In the example of the antenna, earth ground will be written next to the symbol, avoiding any confusion with regular grounding and keeping you from running a bunch of wires from your Speak & Spell out the window and into the garden.

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